The title compound, (C(6)H(7)N(2)O)[FeCl(4)], contains two carbamylpyridinium (picolinamidinium) cations, which are linked into chains by N(+)-H⋯O hydrogen bonds formed between protonated pyridyl N atoms and carbonyl groups. Tetra-chloridoferrate(III) anions lie between these chains, accepting N-H⋯Cl hydrogen bonds from both H atoms of the picolinamidium -NH(2) group.