Preparation and characterization of nanoparticle-doped polymer inclusion membranes: Application to the removal of arsenate and phosphate from waters
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Preparation and characterization of nanoparticle-doped polymer inclusion membranes : Application to the removal of arsenate and phosphate from waters. / Anticó, Enriqueta; Vera, Ruben; Vázquez, Francisco; Fontàs, Clàudia; Lu, Changyong; Ros, Josep.
In: Materials, Vol. 14, No. 4, 878, 2021.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Preparation and characterization of nanoparticle-doped polymer inclusion membranes
T2 - Application to the removal of arsenate and phosphate from waters
AU - Anticó, Enriqueta
AU - Vera, Ruben
AU - Vázquez, Francisco
AU - Fontàs, Clàudia
AU - Lu, Changyong
AU - Ros, Josep
N1 - Funding Information: Funding: This research was funded by Spanish government through project research project PID2019-107033GB-C22 (AEI/FEDER/UE).
PY - 2021
Y1 - 2021
N2 - Nanoparticle-doped polymer inclusion membranes (NP-PIMs) have been prepared and characterized as new materials for the removal of arsenate and phosphate from waters. PIMs are made of a polymer, cellulose triacetate (CTA), and an extractant, which interacts with the compound of interest. We have used the ionic liquid (IL) trioctylmethylammonium chloride (Aliquat 336) as the extractant and have investigated how the addition of nanoparticles can modify membrane prop-erties. To this end, inorganic nanoparticles, such as ferrite (Fe3O4), SiO2 and TiO2, and multiwalled carbon nanotubes (MWCNTs), were blended with the polymer/extractant mixture. Scanning elec-tron microscopy (SEM), infrared spectroscopy (FT-IR), and contact angle measurements have been used to characterize the material. Moreover, PIM stability was checked by measuring the mass loss during the experiments. Since Aliquat 336 acts as an anion exchanger, the NP-PIMs have been ex-plored in two different applications: (i) as sorbent materials for the extraction of arsenate and phosphate anions; (ii) as an organic phase for the separation of arsenate and phosphate in a three-phase system. The presence of oleate-coated ferrite NP in the PIM formulation represents an improvement in the efficiency of NP-PIMs used as sorbents; nevertheless, a decrease in the transport efficiency for arsenate but not for phosphate was obtained. The ease with which the NP-PIMs are prepared suggests good potential for future applications in the treatment of polluted water. Future work will address three main aspects: firstly, the implementation of the Fe3O4-PIMs for the removal of As(V) in real water containing complex matrices; secondly, the study of phosphate recovery with other cell designs that allow large volumes of contaminated water to be treated; and thirdly, the investigation of the role of MWCNTs in PIM stability.
AB - Nanoparticle-doped polymer inclusion membranes (NP-PIMs) have been prepared and characterized as new materials for the removal of arsenate and phosphate from waters. PIMs are made of a polymer, cellulose triacetate (CTA), and an extractant, which interacts with the compound of interest. We have used the ionic liquid (IL) trioctylmethylammonium chloride (Aliquat 336) as the extractant and have investigated how the addition of nanoparticles can modify membrane prop-erties. To this end, inorganic nanoparticles, such as ferrite (Fe3O4), SiO2 and TiO2, and multiwalled carbon nanotubes (MWCNTs), were blended with the polymer/extractant mixture. Scanning elec-tron microscopy (SEM), infrared spectroscopy (FT-IR), and contact angle measurements have been used to characterize the material. Moreover, PIM stability was checked by measuring the mass loss during the experiments. Since Aliquat 336 acts as an anion exchanger, the NP-PIMs have been ex-plored in two different applications: (i) as sorbent materials for the extraction of arsenate and phosphate anions; (ii) as an organic phase for the separation of arsenate and phosphate in a three-phase system. The presence of oleate-coated ferrite NP in the PIM formulation represents an improvement in the efficiency of NP-PIMs used as sorbents; nevertheless, a decrease in the transport efficiency for arsenate but not for phosphate was obtained. The ease with which the NP-PIMs are prepared suggests good potential for future applications in the treatment of polluted water. Future work will address three main aspects: firstly, the implementation of the Fe3O4-PIMs for the removal of As(V) in real water containing complex matrices; secondly, the study of phosphate recovery with other cell designs that allow large volumes of contaminated water to be treated; and thirdly, the investigation of the role of MWCNTs in PIM stability.
KW - Arsenate
KW - Multiwalled carbon nanotubes
KW - Nanoparticles
KW - Phosphate
KW - Polymer inclusion membranes
KW - Removal
U2 - 10.3390/ma14040878
DO - 10.3390/ma14040878
M3 - Journal article
C2 - 33673298
AN - SCOPUS:85100839192
VL - 14
JO - Materials
JF - Materials
SN - 1996-1944
IS - 4
M1 - 878
ER -
ID: 306674478